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CAS 569-61-9 | Pararosaniline Hydrochloride

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Common NamePararosaniline Hydrochloride
CAS Number569-61-9Molecular Weight323.819
Density0.999 g/mL at 20 °CBoiling Point568.2ºC at 760mmHg
Molecular FormulaC19H18ClN3Melting Point250 °C
MSDSChineseUSAFlash Point11 °C
Symbol
GHS08
Signal WordDanger

Names

Namepararosaniline
SynonymMore Synonyms

Pararosaniline Hydrochloride BiologicalActivity

DescriptionPararosaniline hydrochloride is a pH-responsive basic dye, as a biological stain to track certain proteins. Pararosaniline hydrochloride has been used in the analysis of SO2 and formaldehyde and staining of bacteria or other organisms[1][2].
Related CatalogResearch Areas >>OthersSignaling Pathways >>Others >>Others
References

[1]. Yaagoob IY, et al. A resin containing motifs of maleic acid and glycine: a super-adsorbent for adsorptive removal of basic dye pararosaniline hydrochloride and Cd(II) from water. J Environ Health Sci Eng. 2021 Jun 17;19(2):1333-1346.

[2]. Barun Kumar Nandi, et al. Removal of Pararosaniline Hydrochloride Dye (Basic Red 9) from Aqueous Solution by Electrocoagulation: Experimental, Kinetics, and Modeling. Journal of Dispersion Science and Technology. Volume 34, 2013 - Issue 12. 1713-1724

Chemical & Physical Properties

Density0.999 g/mL at 20 °C
Boiling Point568.2ºC at 760mmHg
Melting Point250 °C
Molecular FormulaC19H18ClN3
Molecular Weight323.819
Flash Point11 °C
Exact Mass323.118927
PSA75.89000
LogP5.86280
Index of Refractionn20/D 1.334
InChIKeyJUQPZRLQQYSMEQ-UHFFFAOYSA-N
SMILESCl.N=C1C=CC(=C(c2ccc(N)cc2)c2ccc(N)cc2)C=C1
Storage conditionStore at RT.
StabilityStable. Incompatible with strong oxidizing agents.
Water Solubility10 G/L (25 ºC)

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CX9850100
CHEMICAL NAME :
Benzenamine, 4-((4-aminophenyl)(4-imino-2,5-cyclohexadien-1-yliden e)methyl), monohydrochloride
CAS REGISTRY NUMBER :
569-61-9
LAST UPDATED :
199710
DATA ITEMS CITED :
36
MOLECULAR FORMULA :
C19-H17-N3.Cl-H
MOLECULAR WEIGHT :
323.85
WISWESSER LINE NOTATION :
L6Y DHJ AUM DYR DZ&R DZ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
18200 mg/kg/13W-C
TOXIC EFFECTS :
Endocrine - thyroid weight (goiter) Related to Chronic Data - death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
728 mg/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Endocrine - thyroid tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1714 mg/kg/43W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
364 mg/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Liver - tumors Endocrine - adrenal cortex tumors

MUTATION DATA

TYPE OF TEST :
DNA adduct
TEST SYSTEM :
Mammal - species unspecified Lymphocyte
DOSE/DURATION :
10 pph
REFERENCE :
BIPMAA Biopolymers. (John Wiley & Sons, Inc., 605 Third Ave., New York, NY 10158) V.1- 1963- Volume(issue)/page/year: 11,2537,1972 *** REVIEWS *** IARC Cancer Review:Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,215,1993 IARC Cancer Review:Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 4,57,1974 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 4,57,1974 IARC Cancer Review:Human Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,215,1993 IARC Cancer Review:Group 2B IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 57,215,1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M1440 No. of Facilities: 148 (estimated) No. of Industries: 4 No. of Occupations: 6 No. of Employees: 494 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M1440 No. of Facilities: 165 (estimated) No. of Industries: 4 No. of Occupations: 6 No. of Employees: 907 (estimated) No. of Female Employees: 733 (estimated)

Safety Information

Symbol
GHS08
Signal WordDanger
Hazard StatementsH350
Precautionary StatementsP201-P308 + P313
Personal Protective EquipmentEyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard CodesT: Toxic;
Risk PhrasesR45
Safety Phrases7-16-53-45-36/37
RIDADRUN 2924 3/PG 2
WGK Germany3
RTECSCX9850000
HS Code32041300

Customs

HS Code2921499090
Summary2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

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Synonyms

fuchsinesp
Basic Red 9
Basic red 9 (p-Rosaniline HCl) (C.I. 42500)
4,4'-(4-Iminocyclohexa-2,5-dienylidenemethylene)dianiline Monohydrochloride
Paramagenta hydrochloride
Parafuchsin hydrochlorid
pararosaniline chloride
Orient Paramagenta Base
p-Rosaniline hydrochloride
Paraosaniline hydrochloride
Parafuchsin hydrochloride
4,4'-[(4-iminocyclohexa-2,5-dien-1-ylidene)methanediyl]dianiline hydrochloride (1:1)
Fuchsin SP
MAGENTA 1
FUCHSIN
Basic Rubine
p-Rosaniline Chloride
AFB STAIN
4,4'-[(4-Imino-2,5-cyclohexadien-1-ylidene)methylene]dianiline hydrochloride (1:1)
MFCD00001657
benzenamine, 4,4'-[(4-imino-2,5-cyclohexadien-1-ylidene)methylene]bis-, monohydrochloride
ROSANILINE
BASIC FUCHSIN
4,4'-[(4-Iminocyclohexa-2,5-dien-1-ylidene)methylene]dianiline hydrochloride (1:1)
EINECS 211-189-6
pararosaniline monohydrochloride
fuchsinsp
tris(4-aminophenyl)methylium chloride
FUCHSINE
a-(p-Aminophenyl)-a-(4-imino-2,5-cyclohexadien-1-ylidene)-4-toluidine Monohydrochloride
Benzenamine, 4-[(4-aminophenyl)(4-imino-2,5-cyclohexadien-1-ylidene)methyl], monohydrochloride
MAGENTA
Benzenamine, 4,4'-[(4-imino-2,5-cyclohexadien-1-ylidene)methylene]bis-, hydrochloride (1:1)
Pararosaniline hydrochloride

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