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Naphthol AS | CAS 92-77-3

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Naphthol AS Basic information

Product Name:Naphthol AS
Synonyms:NAPTHOL AS;NAPHTHOL AS(TM);NAPHTHOL AS;TEREPHTHALBIS(O-HYDROXYANILIDE);Dycosthol AS;Kako Grounder AS;Naphtanilide RC;Orange Base GC
CAS:92-77-3
MF:C17H13NO2
MW:263.29
EINECS:202-188-1
Product Categories:Fluorescent;Naphthalene;Organics;Intermediates of Dyes and Pigments
Mol File:92-77-3.mol

Naphthol AS Chemical Properties

Melting point 246-248 °C(lit.)
Boiling point 406.53°C (rough estimate)
density 1.1138 (rough estimate)
refractive index 1.4500 (estimate)
storage temp. Refrigerator
solubility Insoluble in water; sparingly soluble in ethanol
form Powder
Colour Index 37505
pka9.70(at 25℃)
color Beige
PH RangeNon& uorescence (8.2) to yellow/green & uorescence (10.3)
λmax394nm
Major ApplicationSensors, recording materials, photovoltaic cells, copying materials, photoreceptors, lithographic printing plates, inks, toner, paints, textiles, detecting cancer
CAS DataBase Reference92-77-3(CAS DataBase Reference)
EPA Substance Registry System3-Hydroxy-2-naphthanilide (92-77-3)

Safety Information

Hazard Codes Xi,N
Risk Statements 43-51/53
Safety Statements 36/37-61
RIDADR UN 3077 9/PG 3
WGK Germany 1
RTECS QJ1897400
10-21
HazardClass 9
PackingGroup III
HS Code 29242990

MSDS Information

ProviderLanguage
Naphthol AS English
SigmaAldrich English
ACROS English

Naphthol AS Usage And Synthesis

Chemical PropertiesPreparationContact allergensProperties and Applications
DescriptionNaphtol AS is a coupling agent in cotton dying.Occupational dermatitis was reported in a womaninvolved in needlework, probably sensitized fromoccupational contact with clothes.
beige powder
UsesNaphtol AS was used as off-the-shelf color-based anion sensors in organic solvents.
aniline and 3-Hydroxy-2-naphthoic acid?condensation.
HazardLow toxicity by ingestion.
Naphthol AS is a coupling agent in cotton dyeing, inducingoccupational dermatitis or contact allergy in consumersin contact with cotton-dyed clothing. It has beenindirectly reported as a cause of occupational allergy dueto its coupling with Diazo Component 51, or as a crosssensitizeror sensitizer associated with Pigment Red 23in red parts of tattoos. Pigmented contact dermatitis isusual in patients with a high phototype.
Purification MethodsCrystallise it from xylene or AcOH which forms plates m 243-244o [Schnopper et al. Anal Chem 31 1542 1959]. [Beilstein 12 H 505.]
rice or small red powder, melting point of 243 ~ 244 ℃, more sensitive to the air. In sodium hydroxide solution for yellow in liquid, insoluble in water and sodium carbonate solution, slightly soluble in ethanol, soluble in hot the difficulties. This product is widely used in the cotton fabric dyeing and printing. Dyeing cotton, cotton affinity is low, medium coupled ability. Can also be used for cotton yarn, polyester/cotton, PVA, viscose, silk and vinegar fiber dyeing, also can undertake direct printing, and reactive dye printing and cotton fabrics with the dye printing, discharge printing, the reactive dyes color printing and dyeing, and used to make quick pigment, fast amine element, element and organic pigment fast sulfonylurea medications.

Naphthol AS Preparation Products And Raw materials

Raw materialsSodium carbonate-->Phosphorus trichloride-->Aniline-->Chlorobenzene-->3-Hydroxy-2-naphthoic acid-->3-Hydroxy-2-naphthoic acid-->Aniline-->1-Naphthylamine
Preparation ProductsPigment Red 21-->Master-batches-->Pigment Fast Scarlet G-->Bronze Red-->Coating Brilliant Red-->Pigment Permanent Red RB-->Pigment Red 22-->Scarlet 808-->4,4'-bis[[2-hydroxy-3-[(phenylamino)carbonyl]-1-naphthyl]azo][1,1'-biphenyl]-2,2'-disulphonic disodium acid

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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