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Solvent Red 49 | CAS 509-34-2

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Solvent Red 49 Basic information

Product Name:Solvent Red 49
Synonyms:D AND C RED NO 19;D AND C RED NO 37;3',6'-bis(diethylamino)spiro[isobenzofuran-1(3H),9'-[9H]xanthene]-3-one;RHODAMINE B BASE 99%;Oil Pink B;Spiroisobenzofuran-1(3H),9-9Hxanthen-3-one, 3,6-bis(diethylamino)-;SOLVENT RED BN;3',6'-bis(diethylamino)- Spiro[isobenzofuran-1(3H),9'-(9H)xanthen]-3-one
CAS:509-34-2
MF:C28H30N2O3
MW:442.55
EINECS:208-096-8
Product Categories:Solvent Dyestuff;Organics
Mol File:509-34-2.mol

Solvent Red 49 Chemical Properties

Boiling point 553.14°C (rough estimate)
density 1.1536 (rough estimate)
vapor pressure 0Pa at 25℃
refractive index 1.5800 (estimate)
storage temp. room temp
solubility ethanol: 1mg/mL
form Fine Crystalline Powder
Colour Index 45170:1
pKa5.80±0.20(Predicted)
color Lilac
Water Solubility 4.83g/L at 30℃
λmax544 nm
ε(extinction coefficient)≥103000 at 542-546nm in methanol at 0.0025g/L
LogP3.649 at 25℃
CAS DataBase Reference509-34-2(CAS DataBase Reference)
EPA Substance Registry SystemC.I. Solvent Red 49 (509-34-2)

Safety Information

Hazard Codes Xn
Risk Statements 22-37/38-41
Safety Statements 26-36/37
WGK Germany 3
HS Code 32041300

MSDS Information

ProviderLanguage
3',6'-Bis(diethylamino)spiro[isobenzofuran-1(3H),9'-[9H]xanthene]-3-one English
ACROS English
SigmaAldrich English

Solvent Red 49 Usage And Synthesis

UsesPurification Methods
Chemical PropertiesLILAC FINE CRYSTALLINE POWDER
Rhodamine B base is a fluorescent biological staining dye. Rhodamine B base is also used as a laser dye, tunable around 610 nm with the fluorescence yield being temperature dependent. Dyes and metabolites, Environmental Testing
Biological ActivityRhodamine B base has been used as a marker in the experiment to determine the mating of B. thuringiensis-resistant females with B. thuringiensis-resistant and B. thuringiensis-susceptible males in reciprocal orders.
Major impurities are partially dealkylated compounds not removed by recrystallisation. Purify the dye by chromatography, using ethyl acetate/isopropanol/ammonia (conc)(9:7:4, RF 0.75 on Kieselgel G). It has also been crystallised from a concentrated solution in MeOH by slow addition of dry diethyl ether; or from EtOH containing a drop of conc HCl by slow addition of ten volumes of dry diethyl ether. The solid is washed with ether and air dried. The dried material has also been extracted with *benzene to remove oil-soluble material prior to recrystallisation. Store it in the dark. [Beilstein 18 II 486, 18 III/IV 8246, 19/8 V 669.]
Properties and Applications

TEST ITEMS

SPECIFICATION

APPEARANCE

PINK POWDER

SHADE

BLUISH

HEAT RESISTANCE

180 °C min

LIGHT FASTNESS

4-5

ACID RESISTANCE

4

ALKALI RESISTANCE

5

WATER RESISTANCE

5

DENSITY

1.30 g/cm 3

RESIDUE ON 80 MESH

5.0% max

WATER SOLUBLE

1.0% max

VOLATITE 105 °C

1.0% max

TINTING STRENGTH

100-105 %

Solvent Red 49 Preparation Products And Raw materials

Raw materialsPhthalic anhydride-->2-Cyclohexyl-2-geranylmalonic acid-->FLUORESCEIN CHLORIDE-->3-Diethylaminophenol-->Diethylamine-->Phthalic anhydride
Preparation Products2-(4-Diethylamino-2-hydroxybenzoyl)benzoic acid

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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