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Basic Orange 2 | CAS 532-82-1

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Basic Orange 2 Basic information

Product Name:Basic Orange 2
Synonyms:4-Phenylazo-m-phenylenediamine monohydrochloride;chrysoidine orange;4-PHENYLAZO-M-PHENYLENE DIAMINE HYDROCHLORIDE;4-PHENYLAZO-1,3-PHENYLENEDIAMINE MONOHYDROCHLORIDE;1,3-BENZENEDIAMINE, 4-(PHENYLAZO), MONOHYDROCHLORIDE;2,4-DIAMINOAZOBENZENE HYDROCHLORIDE;BASIC ORANGE 2;BASIC ORANGE
CAS:532-82-1
MF:C12H13ClN4
MW:248.71
EINECS:208-545-8
Product Categories:Solvent Dyestuff;Dyes and Pigments;Organics;Azo
Mol File:532-82-1.mol

Basic Orange 2 Chemical Properties

Melting point 235 °C (dec.)(lit.)
Boiling point 2262°C
density 1.2171 (rough estimate)
refractive index 1.6110 (estimate)
storage temp. room temp
solubility Soluble in water, ethanol, acetone, methyl cellosolve, xylene; practically insoluble in Ibenzene
Colour Index 11270
form Crystalline Powder
color Bordeaux to deep purple
PH RangeOrange (4.0) to yellow (7.0)
OdorOdorless
λmax449nm
Merck 13,2279
BRN 3724653
Major ApplicationRecording materials, waveguides, thin solid films, photographic materials, printing plates, inks, toners, detergents, corrosion inhibitors, rubber, textiles, hair dyes
Cosmetics Ingredients FunctionsHAIR DYEING
InChIKeyMCTQNEBFZMBRSQ-GEEYTBSJSA-N
CAS DataBase Reference532-82-1(CAS DataBase Reference)
IARC3 (Vol. 8, Sup 7) 1987
EPA Substance Registry SystemC.I. Basic Orange 2, monohydrochloride (532-82-1)

Safety Information

Hazard Codes N,Xn
Risk Statements 50/53-68-41-38-22
Safety Statements 60-61-46-36/37/39-26-23
RIDADR UN 3077 9/PG 3
WGK Germany 2
RTECS ST3380000
HS Code 32129000
Hazardous Substances Data532-82-1(Hazardous Substances Data)
Toxicitymma-sat 50 mg/plate MUREAV 44,9,77

MSDS Information

ProviderLanguage
ACROS English
SigmaAldrich English

Basic Orange 2 Usage And Synthesis

UsesGeneral DescriptionReactivity ProfileFire HazardProperties and Applications
Chemical PropertiesBORDEAUX TO DEEP PURPLE CRYSTALLINE POWDER
Orange dye for cotton and silk.
DefinitionA dye made from aniline.
Red-brown powder, large black shiny crystals with a green luster or purple powder.
Air & Water ReactionsAzo dyes can be explosive when suspended in air at specific concentrations.Slightly soluble in water.
Basic Orange 2 is an azo compound. Toxic gases are formed by mixing compounds containing azo groups with acids, aldehydes, amides, carbamates, cyanides, inorganic fluorides, halogenated organics, isocyanates, ketones, metals, nitrides, peroxides, phenols, epoxides, acyl halides, and strong oxidizing or reducing agents. Flammable gases are formed by mixing materials in this group with alkali metals. Explosive combination can occur with strong oxidizing agents, metal salts, peroxides, and sulfides. Basic Orange 2 is incompatible with strong oxidizing agents.
HazardQuestionable carcinogen.
Flash point data for Basic Orange 2 are not available. Basic Orange 2 is probably combustible.
Safety ProfileModerately toxic by ingestion and subcutaneous routes. Questionable carcinogen with experimental tumorigenic data. Mutation data reported. When heated to decomposition it emits very toxic fumes of NO, and HCl. Used as a colorant in textiles, paper, leather, inks, wood, and biological stains

TEST ITEMS

SPECIFICATION

APPEARANCE

ORANGE

LIGHTING

1-2

SOAPING

3-4

PERSPIRATING

3-4

FRICTION(DRY)

4

FRICTION(WET)

3

RESIDUE ON 80 MESH

5.0% max

WATER SOLUBILE

1.0% max

VOLATITE 105°C

1.0% max

TINTING STRENGTH

100-105 %

WEIGHT METAL TOTAL

50ppm max

Purification MethodsIt is a red-brown powder which is recrystallised from H2O. It gives a yellow solution in conc H2SO4 which turns orange on dilution. Its solubility at 15o is 5.5% (H2O), 4.75% (EtOH), 6.0% (cellosolve), 9.5% (ethylene glycol), 0.005% (xylene) and is insoluble in *C6H6. The hydroiodide has m 184o (from EtOH) and the picrate forms red needles m 196o. [Muramatsu Bull Chem Soc Jpn 31 864 1958, Beilstein 6 IV 561.]

Basic Orange 2 Preparation Products And Raw materials

Raw materialsSodium nitrite-->m-Phenylenediamine-->Potassium iodide statch paper-->Aniline-->m-Phenylenediamine
Preparation ProductsTartrazine-->Nizatidine-->Fast Scarlet RC Base-->Idebenone-->Folic acid-->Hyodeoxycholic acid-->dicadmium selenide sulphide-->2-Amino-4-nitro anisidine-->1-Methoxy-2,4-dinitrobenzene-->Glucose oxidase-->AMIPROFOS METHYL-->PHOSPHOMOLYBDIC ACID-->5,7-Dichloro-8-hydroxyquinoline

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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