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Vat Blue 4 | CAS 81-77-6

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Vat Blue 4 Basic information

Product Name:Vat Blue 4
Synonyms:14,18-anthrazinetetrone,6,15-dihydro-9;6,15-dihydroanthrazine-5,9,14,18-tetrone;anthraquinonedeepblue;aticvatbluexrn;benzadonebluers;bleusolanthrene;blueanthraquinonepigment;6,15-Dihydro-5,9,14,18-anthrazinetetrone, Pigment Blue 60
CAS:81-77-6
MF:C28H14N2O4
MW:442.42
EINECS:201-375-5
Product Categories:
Mol File:81-77-6.mol

Vat Blue 4 Chemical Properties

Melting point 470-500°C
Boiling point 553.06°C (rough estimate)
density 1.3228 (rough estimate)
refractive index 1.5800 (estimate)
storage temp. Sealed in dry,Room Temperature
form powder to crystal
pka-1.40±0.20(Predicted)
Colour Index 69800
color Dark red to Dark purple to Dark blue
Water Solubility <0.1 g/100 mL at 21 ºC
Merck 14,4934
Stability:Incompatible with strong oxidizing agents.
Cosmetics Ingredients FunctionsCOLORANT
LogP1.78 at 20℃
EPA Substance Registry SystemC.I. Pigment Blue 60 (81-77-6)

Safety Information

Risk Statements 20/21/22
Safety Statements 22-36/37/39
RTECS CB8761100
HS Code 3204.15.8000
Hazardous Substances Data81-77-6(Hazardous Substances Data)
ToxicityLD50 oral in rat: 2gm/kg

MSDS Information

ProviderLanguage
Vat Blue 4 English

Vat Blue 4 Usage And Synthesis

UsesUsesDefinitionGeneral DescriptionFire HazardSynthesisPurification Methods
Chemical Propertiesblue needles with a metallic lustre
Mainly to dye cotton.
UsesIndanthrone (Pigment Blue 60) functions as a blue pigment or as a dye.
Dinaphtho[2,3-a:2'',3''-h]phenazine-5,9,14,18(6H,15H)-tetraone is a pigment; used in preparation of Polyethylene composite material for outdoor building materials.
Preparation(a) in potassium nitrate, LvSuanJia, glucose or organic acid salt (such as formic acid potassium or acetic acid potassium or the mixture of both) under the existence of, with potassium hydroxide treatment 2-Aminoanthracene-9,10-dione;
A blue vat dye or pigment. The molecule consists oftwo anthraquinone nuclei linked through two –NHgroups.
ReactionsAs a pigment, indanthrone is a particulate, insoluble solid dispersed directly into a vehicle, whereas as a dye it is reduced to a base-soluble hydroquinone derivative and then reoxidized onto a solid substrate.
Blue needles with a metallic luster or fine fluffy deep blue powder.
Air & Water ReactionsInsoluble in water.
Flash point data for Vat Blue 4 are not available. Vat Blue 4 is probably combustible.
Flammability and ExplosibilityNot classified
Indanthrone , Indanthren Blue RSand R, is prepared from 2- (or1-) aminoanthraquinone by potash fusion , in potassium phenolate , , orin 50 % potassium hydroxide , .
Chlorination of indanthrone in sulfuric acidunder addition of 1 % or5%manganese dioxide(5 – 8 % or 13.8 – 14 % Cl) at 50 – 55 ?C affords dyes of slightly greener shades (Indanthren BlueGCD or BC).
Properties and Applicationsred light blue. Slightly soluble in chloroform (heat), o-chlorophenol,Quinoline, insoluble in acetic acid, acetone, ethanol, pyridine, toluene, xylene. The strong sulfuric acid for brown, after diluted blue precipitation; In alkaline insurance powder solution for blue, acidic solutions for the red light in blue. And C.I. Vat ?Blue 4, C.I. Pigment Blue 60 the same chemical structure.
Crystallise indanthrene repeatedly from 1,2,4-trichlorobenzene to give a blue powder. It is soluble in alkali and conc H2SO4. [Weinstein & Merritt J Am Chem Soc 81 3759 1959, Beilstein 24 II 317, 24 III/IV 2193.]

Vat Blue 4 Preparation Products And Raw materials

Raw materialsSodium nitrite-->Potassium hydroxide-->Sodium acetate-->Sodium dithionite-->Sodium acetate trihydrate-->Oleic acid-->Sodium nitrate-->2-AMINOANTHRAQUINONE-->Mixed alkalis-->5,9,14,18-Anthrazinetetrone-->2-amino-1-chloroanthraquinone-->2-Imidazolidinone,1,3,4-trimethyl--->1-Aminoanthraquinone-->Naphthalene-->2-AMINOANTHRAQUINONE-->9,10-dihydro-8-nitro-9,10-dioxoanthracene-1-sulphonic acid-->1-amino-2-bromoanthracene-9,10-dione
Preparation ProductsVat Dark Blue VB-->Vat Blue 14-->Alizarin-->5,9,14,18-Anthrazinetetrol, 6,15-dihydro-, tetrakis(hydrogen sulfate) (ester), tetrasodium salt-->C.I.Vat Blue 10

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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