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Acid Violet 43 | CAS 4430-18-6

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Acid Violet 43 Basic information

Product Name:Acid Violet 43
Synonyms:Brilliant Violet R;Aminyl Violet E-3B;Benzenesulfonic acid 2-[(9, 10-dihydro-4-hydroxy-9, 10-dioxo-1-anthracenyl) aminol-5-methyl], monosodium salt;Egacid Violet 3B;Hastings Light Fast Violet IRS;Suminol Levelling Violet 3B;Triacid Light Violet 3B.;SOLWAY PURPLE
CAS:4430-18-6
MF:C21H16NNaO6S
MW:433.41
EINECS:224-618-7
Product Categories:Dyes and Pigments;Organics;Aminoanthraquinones;Anthraquinones;Hydroxyanthraquinones
Mol File:4430-18-6.mol

Acid Violet 43 Chemical Properties

density 0.513[at 20℃]
vapor pressure 0.072Pa
storage temp. Hygroscopic, -20°C Freezer, Under inert atmosphere
solubility Methanol (Slightly), Water (Slightly)
Colour Index 60730
form Solid
color Dark Purple to Black
Water Solubility 1.708-50.3g/L at 20-28℃
Stability:Stable for 4 hours in acetone/olive oil (6.05 and 151 mg active dye/ml) and purified water (3.03 and 121 mg active dye/ml) at room temperature, protected from light and under inert gas atmosphere. Deviation from initial value was between – 4 % and 6 % after 4 hours (only tested for Jarocol Violet 43, Batch No. 10130)
Cosmetics Ingredients FunctionsHAIR DYEING
COLORANT
InChIInChI=1S/C21H15NO6S.Na.H/c1-11-6-7-14(17(10-11)29(26,27)28)22-15-8-9-16(23)19-18(15)20(24)12-4-2-3-5-13(12)21(19)25;;/h2-10,22-23H,1H3,(H,26,27,28);;
InChIKeyGTKIEPUIFBBXJQ-UHFFFAOYSA-M
SMILESN(C1C=CC(C)=CC=1S(O)(=O)=O)C1=CC=C(O)C2C(C3=CC=CC=C3C(=O)C1=2)=O.[NaH]
LogP-0.66-1.29 at 22-25℃
EPA Substance Registry SystemC.I. Acid Violet 43 (4430-18-6)

Safety Information

Risk Statements 36
Safety Statements 24/25-26
HS Code 32041200

MSDS Information

Acid Violet 43 Usage And Synthesis

Chemical PropertiesUsesFlammability and ExplosibilitySafety
DescriptionAcid Violet 43 is an anthraquinone color that functions as a colorant in cosmetic formulations (Wenninger, Canterbery, and McEwen 2000). Batches of Acid Violet 43 that are certified by the Food and Drug Administration (FDA) as meeting the standards and specifications described in the Code of Federal Regulations (21 CFR 73 & 74) are named Ext. D & C Violet No. 2 (FDA 1976). Most of the available safety test data are from studies of Ext. D & C Violet No. 2 conducted to support FDA listing this color for drug and cosmetic use.
Soluble in ethanol. Shows blue color in concentrated sulfuric acid and olive brown color with purple precipitate when diluted.
Physical propertiesAcid Violet 43 has a bluish violet hue in daylight and is slightly redder in artificial light (tungsten) (Society of Dyers and Colourists 1971a). It is soluble in alcohol (Society of Dyers and Colourists 1971b) and water (Hazleton Laboratories, Inc. 1968). It is blue in concentrated sulfuric acid, olive-brown after dilution, accompanied by a purple precipitate.
Acid Violet 43 is an anthraquinone colour used in semi-permanent hair dye formulations at a maximum concentration of 0.5% active dye. According to the EU Cosmetics Directive 76/768/EEC, Annex IV Part I List of Colouring Agents, Acid Violet 43 is allowed as CI 60730 in cosmetic products except those intended to come into contact with mucous membranes.
PreparationAcid Violet 43 can be prepared by sulfonating the anthraquinone color, C.I. 60725 and converting it to the sodium salt (Society of Dyers and Colourists 1971b).
Will be 1,4-Dihydroxyanthracene-9,10-dione or anthracene-1,4,9,10-tetraol or 1-Bromo-4-hydroxyanthraquinone (or 1-Chloro-4-hydroxyanthracene-9,10-dione) and reaction p-Methylaniline, then stlfonation, and translated into sodium salt.
Non flammable
Industrial usesAcid violet 43 is used for the dyeing of wool and its products. It can be used for dyeing and printing of wool, silk, nylon and its fabrics, as well as for leather dyeing.
In 2001, the Cosmetic Ingredient Review (CIR) Expert Panel (Panel) published a safety assessment with the conclusion that Acid Violet 43 is safe for use in hair dye formulations when free of impurities except for the following: ≤18% volatile matter (at 135°C) and chlorides and sulfates (calculated as sodium salts); ≤0.4% water-insoluble matter; ≤0.2% 1-hydroxy-9,10-anthracenedione; ≤0.2% 1,4-dihydroxy-9,10-anthracenedione; ≤0.1% p-toluidine; ≤0.2% p-toluidine sulfonic acids, sodium salts; ≤1% subsidiary colors; ≤20 ppm lead (as Pb); ≤3 ppm arsenic (as As); ≤1 ppm mercury as (Hg); and ≥80% total color.
Amended Safety Assessment of Acid Violet 43 as Used in Cosmetics
Properties and Applicationsblue purple. Soluble in alcohol. The strong sulfuric acid in blue, diluted for olive brown, then a purple precipitation.
Standard Light Fastness Soaping Persperation Fastness Oxygen bleaching Fastness to seawater
Fading Stain Fading Stain Fading Stain
ISO 5 1-2 1-2 3-4 1 5 2 1
AATCC 3 1 1 2 1 1 2 2

Acid Violet 43 Preparation Products And Raw materials

Raw materials1,4-Dihydroxyanthraquinone-->1-bromo-4-hydroxyanthraquinone-->1,4-Dihydroxyanthraquinone-->p-Toluidine-->1-chloro-4-hydroxyanthraquinone

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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