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Naphthol AS-D | CAS 135-61-5

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Naphthol AS-D Basic information

Product Name:Naphthol AS-D
Synonyms:1-(2',3'-Hydroxynaphthoylamino)-2-methylbenzene;2-Naphtho-o-toluidide, 3-hydroxy-;3-hydroxy-n-(2-methylphenyl)-2-naphthalenecarboxamid;Acco Naf-Sol AS-D;Acco Naphthol AS-D;Acna Naphthol E;AcnaNaphtholE;Amanil Naphthol AS-D
CAS:135-61-5
MF:C18H15NO2
MW:277.32
EINECS:205-205-0
Product Categories:Substrates;Intermediates of Dyes and Pigments
Mol File:135-61-5.mol

Naphthol AS-D Chemical Properties

Melting point 196-198 °C
Boiling point 399.7±35.0 °C(Predicted)
density 1.277±0.06 g/cm3(Predicted)
pka8.73±0.40(Predicted)
Colour Index 37520
form powder to crystal
color White to Gray to Brown
NIST Chemistry Reference2-Naphthalenecarboxamide, 3-hydroxy-n-(2-methylphenyl)-(135-61-5)
EPA Substance Registry System2-Naphthalenecarboxamide, 3-hydroxy-N-(2-methylphenyl)- (135-61-5)

Safety Information

Hazard Codes N
Risk Statements 50/53
Safety Statements 60-61
RIDADR UN 3077 9/PG 3
WGK Germany 2
HS Code 2924.29.7790
HazardClass 9
PackingGroup III

MSDS Information

ProviderLanguage
SigmaAldrich English

Naphthol AS-D Usage And Synthesis

PreparationPurification Methods
Chemical PropertiesBeige powder. Soluble in solvent naphtha. Insoluble in water and soda ash solution.
O-Methylaniline and 3-Hydroxy-2-naphthoic acid condensation.
Flammability and ExplosibilityNon flammable
Purify it by recrystallisation from xylene. This gives yellow-green fluorescent solutions at pH 8.2-9.5. [IR: Schnopper et al. Anal Chem 31 1542 1959.] The naphthol AS-D acetate is obtained with AcCl, m 168-169o, and with chloroacetyl chloride naphthol AS-D-chloroacetate is obtained [Moloney et al. J Histochem Cytochem 8 200 1960, Burstone Arch Pathology 63 164 1957]. [Beilstein 12 H 505.]
Properties and Applicationsyellowish powder, melting point for 195 ~ 196 ℃. Insoluble in water solution and sodium carbonate, soluble in naphtha. In sodium hydroxide solution for yellow. Sensitive to air. Mainly used for cotton yarns, cotton fabric, PVA, viscose, silk and vinegar fiber dyeing, also can be used for direct printing, the cotton print and dye discharge printing, and can be used as a quick pigment and organic pigments intermediate. The affinity of cotton is low, medium coupled ability.

Naphthol AS-D Preparation Products And Raw materials

Raw materialsCarbon dioxide-->Phosphorus trichloride-->Chlorobenzene-->o-Toluidine-->3-Hydroxy-2-naphthoic acid-->3-Hydroxy-2-naphthoic acid-->o-Toluidine
Preparation ProductsPigment Red 13-->Chromate(3-), bis[3-(hydroxy-κO)-4-[[2-(hydroxy-κO)-3-[[(2-methylphenyl)amino]carbonyl]-1-naphthalenyl]azo-κN1]-7-nitro-1-naphthalenesulfonato(3-)]-, disodium hydrogen

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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