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VAT BLACK 27 | CAS 2379-81-9

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VAT BLACK 27 Basic information

Product Name:VAT BLACK 27
Synonyms:N,N'-(10,15,16,17-tetrahydro-5,10,15,17-tetraoxo-5H-dinaphtho[2,3-a:2',3'-i]carbazole-6,9-diyl)bis(benzamide);Vat Olive Green R;Benzamide, N,N-(10,15,16,17-tetrahydro-5,10,15,17-tetraoxo-5H-dinaphtho2,3-a:2,3-icarbazole-6,9-diyl)bis-;C.I.VATBLACK27;Vat black 27 (C.I. 69005);Anthramar Olive R;Cibanone Olive 2R;Dycosthren Olive R
CAS:2379-81-9
MF:C42H23N3O6
MW:665.65
EINECS:219-169-9
Product Categories:Organics
Mol File:2379-81-9.mol

VAT BLACK 27 Chemical Properties

Boiling point 685.54°C (rough estimate)
density 1.537
refractive index 1.7800 (estimate)
pka11.19±0.20(Predicted)
EPA Substance Registry SystemBenzamide, N,N'-(10,15,16,17-tetrahydro-5,10,15,17-tetraoxo-5H-dinaphtho[2,3-a:2',3'-i]carbazole-6,9-diyl)bis- (2379-81-9)

Safety Information

MSDS Information

VAT BLACK 27 Usage And Synthesis

UsesSynthesisReferences
Chemical PropertiesBlack powder. Insoluble in water, acetone, ethanol, toluene, xylene, slightly soluble in chloroform, pyridine, soluble in o-chlorophenol. Reddish color in concentrated sulfuric acid, produces olive green precipitate with fluorescence after dilution. Reddish brown in alkaline solution of insurance powder, yellowish brown in acidic solution.
Vat Black 27 is a black dye.
Preparation(a) N-(4-chloro-9,10-dioxo-9,10-dihydroanthracen-1-yl)benzamide?and N-(4-amino-9,10-dioxo-9,10-dihydroanthracen-1-yl)benzamide in the presence of copper condensation, then use Chlorosulfonic acid cyclization, (b) N-[4-(4-benzoylimino-9,10-dioxo-anthracen-1-ylidene)amino-9,10-dihydroxy-anthracen-1-yl]benzamide?in sulfuric acid central change, then the product oxidation.
4,4'-Bisbenzoylamino-1,1'-dianthrimide-2,2'-carbazole , Indanthren OliveR, is prepared from 4,4'-bisbenzoylamino-1,1'-dianthrimide by ring closure in concentratedsulfuric acid .
Properties and Applicationsbrown light grey. Black powder. Soluble in 2 – Chlorophenol, slightly soluble in Chloroform and Pyridine , not soluble in Acetone, Etanol, Toluene and Xylene. In concentrated sulfuric acid for red, dilution after flocculent olive green precipitation. Alkaline reduction leuco for red brown; Acid reduction leuco for yellow brown. Mainly used in cotton fiber dyeing, suitable for suspension pad dyeing, also used for cotton yarn of the jig dyeing cotton and the impregnation, rarely used for printing. Can with other VAT dye spell dyed noise. Dyeing silk, affinity and levelness were good, also used for Fiber/cotton blended fabric dyeing.
Standard Ironing Fastness Chlorine bleach Light Fastness Mercerized Oxygen bleach Soaping
Fading Stain
ISO 3 4-5 7 4-5 4-5 4-5 4-5
AATCC 3 4-5 7 4 4-5
[1] Krivov SV, et al.Diffusive reaction dynamics on invariant free energy profiles. Proc Natl Acad Sci U S A. 2008 Sep 16;105(37):13841-6.

VAT BLACK 27 Preparation Products And Raw materials

Raw materialsSulfuric acid-->Copper(II) sulfate-->Copper-->1,2-Dichlorobenzene-->Potassium chlorate-->1-Aminoanthraquinone-->1,4-Diamino anthraquinone-->1,4-Diamino-2,3-dihydroanthraquinone-->1-Chloro anthraquinone
Preparation ProductsVat Brown 68-->Vat Brown 72

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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