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Vat Orange 9 | CAS 128-70-1

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Vat Orange 9 Basic information

Product Name:Vat Orange 9
Synonyms:pyranthrenedione;Pyranthron;Pyranthrone;Romantrene Golden Orange FG;Sandothrene Golden Orange NG;Solanthrene Orange F-J;Solanthrene Orange J;Tinon Golden Orange G
CAS:128-70-1
MF:C30H14O2
MW:406.43
EINECS:204-906-9
Product Categories:Organics
Mol File:128-70-1.mol

Vat Orange 9 Chemical Properties

Boiling point 703.7±30.0 °C(Predicted)
density 1.489
storage temp. Sealed in dry,Room Temperature
NIST Chemistry Reference8,16-Pyranthenedione(128-70-1)
EPA Substance Registry System8,16-Pyranthrenedione (128-70-1)

Safety Information

Safety Statements 22-24/25

MSDS Information

ProviderLanguage
Vat Orange 9 English

Vat Orange 9 Usage And Synthesis

PreparationSynthesis
Chemical PropertiesYellowish brown powder. Insoluble in water, slightly soluble in ethanol, soluble in tetrahydronaphthalene, xylene. Dark blue in concentrated sulfuric acid, produces yellowish brown precipitate when diluted. Bluish red in alkaline insurance powder reducing solution, orange in acidic solution.
8,16-Pyranthrenedione called. (a) 1-(2-Methyl-9,10-dioxoanthracene-1-yl)-2-methylanthracene-9,10-dione in 350 ~ 380 ℃ heat alone, or in low temperature with dehydrant processing, take off 2 Moore water; (b) 1-(2-Methyl-9,10-dioxoanthracene-1-yl)-2-methylanthracene-9,10-dione?aqueous cream content (with or without ammonia or salt all but), in 230 ~ 250 ℃ and under pressure heating 10 to 12 hours; (C) 1-(2-Methyl-9,10-dioxoanthracene-1-yl)-2-methylanthracene-9,10-dione?and Etanol/Potassium hydroxide heating 10 to 12 hours; (d) 1,6-Dibenzoylpyrene?with Aluminium chloride and Sodium chloride melting, and access to oxygen.
Synthesis5,5'-Bisbenzoylamino-1,1'-dianthrimide-2,2'carbazole , Indanthren Golden-Orange 3G, is prepared from 5,5'-bisbenzoylamino-1,1'-dianthrimide by ring closurein concentrated sulfuric acid .
Pyranthrone , (149),is prepared by double ring closure of 2,2'-dimethyl-1,1'-bianthraquinonyl (148), which isobtained from 1-chloro-2-methylanthraquinone(147) by heating with copper powder in odichlorobenzene– pyridine. Ring closure occursunder alkaline conditions, e.g., KOH– isobutanolat 105 ?C ; process improvementsare reported in , . The unsubstitutedpyranthrone and its halogen derivatives are usedas vat dyes and pigments.
Properties and Applicationsyellow orange. Orange powder. Soluble in 1, 2, 3, 4-Tetrahydronaphthalene and Xylene, slightly soluble in alcohol. In the dark for the strong sulfuric acid, dilute yellow brown after precipitation. Alkaline reduction for blue-ray red body hidden color; Acid reduction to orange color body hidden. This product for light brittle dye, cotton fiber in the sunlight has accelerated. With light brittle, general is not used for cotton cloth of monochromatic dyeing, spelling color also should control consumption, but also can directly printing and the discharge, also can be used in viscose, silk dyeing. Dye polyester/cotton blended fabric, of polyester dyeing serious.
Standard Ironing Fastness Chlorine bleach Light Fastness Mercerized Oxygen bleach Soaping
Fading Stain
ISO 4 5 5-6 4-5 4-5 4-5 5
AATCC 4 5 5-6 4-5 5

Vat Orange 9 Preparation Products And Raw materials

Raw materialsChlorine-->Butyric Acid-->N-Methyl-2-pyrrolidone-->2-Methyl anthraquinone-->2,2'-dimethyl-1,1'-bianthraquinone-->Vat Orange 9-->1,6-dibenzoylpyrene
Preparation ProductsVat Black 9-->Vat Orange 2-->C.I. Solubilised Vat Orange 9-->Vat Orange 9-->Vat Black 9-->Vat Orange 4

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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