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SOLVENT GREEN 1 | CAS 510-13-4

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SOLVENT GREEN 1 Basic information

Product Name:SOLVENT GREEN 1
Synonyms:TIMTEC-BB SBB006477;alpha,alpha-bis(p-dimethylaminophenyl)benzyl alcohol;MALACHITE GREEN C.I. NO.42000;4-(dimethylamino)-alpha-(4-(dimethylamino)phenyl)-alpha-phenyl-benzenemethan;alpha,alpha-bis(p-dimethylaminophenyl)-benzylalcoho;4-(Dimethylamino)-α-[4-(dimethylamino)phenyl]-α-phenylbenzenemethanol;4,4'-Bis(dimethylamino)trityl alcohol;Bis[4-(dimethylamino)phenyl]phenylmethanol
CAS:510-13-4
MF:C23H26N2O
MW:346.47
EINECS:208-109-7
Product Categories:
Mol File:510-13-4.mol

SOLVENT GREEN 1 Chemical Properties

Melting point 112-114 °C(lit.)
Boiling point 481.19°C (rough estimate)
density 1.0896 (rough estimate)
refractive index 1.6300 (estimate)
pka13.78±0.29(Predicted)
form Solid
color Green to dark green
CAS DataBase Reference510-13-4(CAS DataBase Reference)
EPA Substance Registry SystemBenzenemethanol, 4-(dimethylamino)-.alpha.-[4-(dimethylamino)phenyl]-.alpha.-phenyl- (510-13-4)

Safety Information

Hazard Codes Xn
Risk Statements 22
WGK Germany 3
RTECS DN8600000

MSDS Information

ProviderLanguage
SigmaAldrich English

SOLVENT GREEN 1 Usage And Synthesis

DefinitionProperties and Applications
UsesMalachite Green Carbinol base (MGOH, MGCB) is a derivative of Malachite green (MG) with not fluorescence. Malachite green carbinol base (MGOH, MGCB), as a pH regulation reagent, MGCB molecule could release OH- under UV light irradiation and generate a progressive shift in pH values. MGCB solution turns from colorless to deep green rapidly when exposed to a high-pressure UV lamp (500 W, 50 W/cm)[1][2].
ChEBI: Malachite Green carbinol is a benzenoid aromatic compound.
Purification MethodsThe oxalate [Beilstein 8 H 326, 13 IV 2279.] is recrystallised from hot water and dried in air. The carbinol is precipitated from the oxalate (1g) in distilled water (100mL) by adding M NaOH (10mL). The precipitate is filtered off, recrystallised from 95% EtOH containing a little dissolved KOH, then washed with ether, and crystallised from pet ether. Dry it in a vacuum at 40o. An acid, almost colourless, solution (2 x 10-5M in 6 x 10-5M H2SO4) rapidly reverts to the coloured dye. [Swain & Hedberg J Am Chem Soc 72 3373 1950, Beilstein 13 H 243, 744.]

TEST ITEMS

SPECIFICATION

APPEARANCE

Malachite Green Powder

SHADE

Bluish

HEAT RESISTANCE

140 °C min

LIGHT FASTNESS

4

ACID RESISTANCE

4

ALKALI RESISTANCE

4

WATER RESISTANCE

5

DENSITY

1.10g/cm 3

RESIDUE ON 80 MESH

5.0% max

WATER SOLUBLE

1.0% max

VOLATITE 105 °C

1.0% max

TINTING STRENGTH

100-105 %

WEIGHT METAL TOTAL

50ppm max

References[1] Yubin Zhou, et al. Organic additives stabilize RNA aptamer binding of malachite green. Talanta. 2016 Nov 1;160:172-182 DOI:10.1016/j.talanta.2016.06.067
[2] Can Xu, et al. Versatile Dual Photoresponsive System for Precise Control of Chemical Reactions. ACS Nano. 2017 Aug 22;11(8):7770-7780. DOI:10.1021/acsnano.7b01450

SOLVENT GREEN 1 Preparation Products And Raw materials

Raw materialsBenzotrichloride-->Benzaldehyde-->N,N-Dimethylaniline

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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